Asymmetric methoxyselenenylations with camphor-based selenium electrophiles

被引:29
作者
Back, TG [1 ]
Nan, S [1 ]
机构
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 19期
关键词
D O I
10.1039/a806707d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The asymmetric methoxyselenenylation of olefins was achieved with a series of camphor-based selenenyl triflates, of which the readily available 2-oxo analog 2a proved the most effective.
引用
收藏
页码:3123 / 3124
页数:2
相关论文
共 23 条
  • [11] FUJITA K, 1995, TETRAHEDRON LETT, V36, P5219
  • [12] Design of optically active selenium reagents having a chiral tertiary amino group and their application to asymmetric inter- and intramolecular oxyselenenylations
    Fujita, K
    Murata, K
    Iwaoka, M
    Tomoda, S
    [J]. TETRAHEDRON, 1997, 53 (06) : 2029 - 2048
  • [13] A HIGHLY SELECTIVE ASYMMETRIC METHOXYSELENYLATION OF ALKENES WITH A CHIRAL FERROCENYLSELENIUM REAGENT
    FUKUZAWA, S
    KASUGAHARA, Y
    UEMURA, S
    [J]. TETRAHEDRON LETTERS, 1994, 35 (50) : 9403 - 9406
  • [14] Asymmetric methoxyselenenylation of alkenes with chiral ferrocenylselenium reagents
    Fukuzawa, S
    Takahashi, K
    Kato, H
    Yamazaki, H
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (22) : 7711 - 7716
  • [15] NAN S, 1998, 80 ANN C CAN SOC CHE
  • [16] PAULMIER C, 1986, SELENIUM REAGENTS IN, pCH7
  • [17] Schmid G. H., 1977, CHEM DOUBLE BONDED F
  • [18] Asymmetric selenomethoxylation of alkenes with camphorselenenyl sulfate
    Tiecco, M
    Testaferri, L
    Santi, C
    Marini, F
    Bagnoli, L
    Temperini, A
    [J]. TETRAHEDRON LETTERS, 1998, 39 (18) : 2809 - 2812
  • [19] DOUBLE DIFFERENTIATION IN ASYMMETRIC METHOXYSELENENYLATION OF TRANS-BETA-METHYLSTYRENE
    TOMODA, S
    FUJITA, K
    IWAOKA, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) : 129 - 131
  • [20] ASYMMETRIC TRANS-ADDITION REACTIONS OF A CHIRAL SELENOBINAPHTHYL WITH PROCHIRAL OLEFINS - THE CASE OF METHOXYSELENENYLATION
    TOMODA, S
    IWAOKA, M
    [J]. CHEMISTRY LETTERS, 1988, (11) : 1895 - 1898