Green photochemistry:: Production of fine chemicals with sunlight

被引：129

作者：

Oelgemoeller, Michael ^{[1
]}

Jung, Christian

Mattay, Jochen

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Dublin City Univ, Natl Inst Cellular Biotechnol, Dublin 9, Ireland

[3] German Aerosp Ctr, D-51147 Cologne, Germany

[4] Univ Bielefeld, Dept Chem, D-33501 Bielefeld, Germany

来源：

PURE AND APPLIED CHEMISTRY | 2007年 / 79卷 / 11期

关键词：

solar chemistry; photoacylation; photooxygenation; green chemistry; photochemistry;

D O I：

10.1351/pac200779111939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three photochemical reactions were investigated under solar irradiation conditions with moderately concentrated sunlight: the photoacylation of naphthoquinone with butyraldehyde and the dye-sensitized photooxygenations of citronellol and 1,5-dihydroxynaphthalene, respectively. All reactions were easily performed on multigram-to-kilogram scales using cheap and commercially available starting materials, and yielded important key intermediates for industrial applications.

引用

页码：1939 / 1947

页数：9

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