Green photochemistry:: Production of fine chemicals with sunlight

被引：129

作者：

Oelgemoeller, Michael ^{[1
]}

Jung, Christian

Mattay, Jochen

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Dublin City Univ, Natl Inst Cellular Biotechnol, Dublin 9, Ireland

[3] German Aerosp Ctr, D-51147 Cologne, Germany

[4] Univ Bielefeld, Dept Chem, D-33501 Bielefeld, Germany

来源：

PURE AND APPLIED CHEMISTRY | 2007年 / 79卷 / 11期

关键词：

solar chemistry; photoacylation; photooxygenation; green chemistry; photochemistry;

D O I：

10.1351/pac200779111939

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three photochemical reactions were investigated under solar irradiation conditions with moderately concentrated sunlight: the photoacylation of naphthoquinone with butyraldehyde and the dye-sensitized photooxygenations of citronellol and 1,5-dihydroxynaphthalene, respectively. All reactions were easily performed on multigram-to-kilogram scales using cheap and commercially available starting materials, and yielded important key intermediates for industrial applications.

引用

页码：1939 / 1947

页数：9

共 53 条

[41] THE BEGINNINGS OF ORGANIC-PHOTOCHEMISTRY [J].

ROTH, HD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09) :1193-1207

[42] Solar light induced photocatalytic oxidation of benzyl alcohol using heteropolyoxometalate catalysts of the type [S2M18O62]4- [J].

Rüther, T ;

Bond, AM ;

Jackson, WR .

GREEN CHEMISTRY, 2003, 5 (04) :364-366

[43] Concept and economic evaluation of an industrial synthesis of ε-caprolactam via solar photooximation of cyclohexane [J].

Sattler, C ;

Müller, FJ ;

Riffelmann, KJ ;

Ortner, J ;

Funken, KH .

JOURNAL DE PHYSIQUE IV, 1999, 9 (P3) :723-727

[44] POLYMER-BASED SENSITIZERS FOR PHOTOOXIDATIONS .2. [J].

SCHAAP, AP ;

THAYER, AL ;

BLOSSEY, EC ;

NECKERS, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) :3741-3745

[45]

Schiel C, 1998, J INFORM REC, V24, P257

[46] Green photochemistry:: the solar-chemical 'photo-Friedel-Crafts acylation' of quinones [J].

Schiel, C ;

Oelgemöller, M ;

Ortner, J ;

Mattay, J .

GREEN CHEMISTRY, 2001, 3 (05) :224-228

[47]

Schiel C, 2001, SYNTHESIS-STUTTGART, P1275

[48] Photooxygenations of 1-naphthols:: an environmentally friendly access to 1,4-naphthoquinones [J].

Suchard, O ;

Kane, R ;

Roe, BJ ;

Zimmerman, E ;

Jung, C ;

Waske, PA ;

Mattay, J ;

Oelgemöller, M .

TETRAHEDRON, 2006, 62 (07) :1467-1473

[49] Synthetic pathways and processes in green chemistry. Introductory overview [J].

Tundo, P ;

Anastas, P ;

Black, DS ;

Breen, J ;

Collins, T ;

Memoli, S ;

Miyamoto, J ;

Polyakoff, M ;

Tumas, W .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1207-1228

[50]

WALSCH T, 1997, SEDES WINDOWS VERSIO

← 1 2 3 4 5 6 →