Energetics of the O-H bond in phenol and substituted phenols: A critical evaluation of literature data

被引：197

作者：

dos Santos, RMB

Simoes, JAM ^{[1
]}

机构：

[1] Univ Lisbon, Fac Ciencias, Dept Quim & Bioquim, P-1700 Lisbon, Portugal

[2] Univ Algarve, Unidad Ciencias & Tecnol Agr, P-8000 Faro, Portugal

[3] Univ Algarve, CiTecMat, P-8000 Faro, Portugal

[4] Univ Lisbon, Fac Ciencias, CiTecMat, P-1700 Lisbon, Portugal

来源：

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA | 1998年 / 27卷 / 03期

关键词：

bond dissociation enthalpy; energetics; phenol; phenolic compounds; substituent effects; substituted phenols; thermochemistry;

D O I：

10.1063/1.556020

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

This review presents a critical assessment of the available experimental information (contained in similar to 90 literature references) on the thermochemistry of the O-H bond in phenol and substituted phenols. The analysis led to a set of recommended values for the O-H bond dissociation enthalpies,;which in turn allowed us to discuss several empirical and theoretical methodologies used to estimate these data. (C) 1998 American Institute of Physics and American Chemical Society.

引用

页码：707 / 739

页数：33

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DETERMINATION OF FORMAL POTENTIALS OF CHEMICALLY UNSTABLE REDOX COUPLES BY 2ND-HARMONIC ALTERNATING-CURRENT VOLTAMMETRY AND CYCLIC VOLTAMMETRY - APPLICATION TO THE OXIDATION OF THIOPHENOXIDE IONS [J].