COMPARISONS OF N-H, C-H, O-H, AND S-H HETEROLYTIC AND HOMOLYTIC BOND STRENGTHS IN AQUEOUS AND DIMETHYL-SULFOXIDE SOLUTION

被引：10

作者：

BAUSCH, MJ

GOSTOWSKI, R

GUADALUPEFASANO, C

SELMARTEN, D

VAUGHN, A

WANG, LH

机构：

[1] Department of Chemistry and Biochemistry, Southern Illinois University at Carbondale, Carbondale

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 26期

关键词：

D O I：

10.1021/jo00026a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Analysis of relative homolytic bond dissociation energy (DELTA-BDE) data for 16 different molecules, obtained via incorporation of aqueous and dimethyl sulfoxide (DMSO) solution acid-base and redox data into thermochemical cycles, indicates that DMSO and water as solvent have minimal differential effects on the homolytic strengths of labile N-H, C-H, O-H, and S-H bonds for the species in this study.

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收藏

页码：7191 / 7193

页数：3

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