Efficient oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran using Mn(III)-salen catalysts

被引：182

作者：

Amarasekara, Ananda S. ^{[1
]}

Green, Dalkeith ^{[1
]}

McMillan, Erinn ^{[1
]}

机构：

[1] Prairie View A & M Univ, Dept Chem, Prairie View, TX 77446 USA

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 02期

基金：

美国国家科学基金会;

关键词：

Mn(III)-salen; oxidation; 5-hydroxymethylfurfural; 2,5-diformylfuran;

D O I：

10.1016/j.catcom.2007.06.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

5-Hydroxymethylfurfural is efficiently oxidized to 2,5-diformylfuran in 63-89% yield using Mn(III)-salen catalysts and sodium hypochlorite, in a pH 11.3 phosphate buffer-CH2Cl2 biphase system at room temperature. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：286 / 288

页数：3

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