Synthesis and rutilelike structure of [Cd(tcm)(hmt)(H2O)](tcm) (tcm- = tricyanomethanide, C(CN)3-; hmt = hexamethylenetetramine)

被引：63

作者：

Batten, SR ^{[1
]}

Hoskins, BF ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期

关键词：

D O I：

10.1021/ic980059v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three-dimensional coordination polymer [Cd(tcm)(hmt)(H(2)O)](tcm) (tcm(-) = tricyanomethanide, C(CN)(3)(-); hmt = hexamethylenetetramine) has a rutilelike topology, with octahedral centers (cadmium atoms) and trigonal centers (hmt ligands and half the tcm anions) in the ratio 1:2. One of the connections of the three-connecting hmt ligands is a hydrogen-bonding interaction with coordinated water ligands.

引用

页码：3432 / +

页数：4

共 32 条

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