共 11 条
[11]
Rennhard H. H., 1973, US Patent, Patent No. [3, 766, 165, 3766165]
Ultrasound promoted glucose oligomerization under Fischer glycosylation conditions: Structural aspects
被引：8
作者：
Brochette, S
Descotes, G
Bouchu, A
Queneau, Y
Lemoine, J
机构：
[1] CNRS, UMR 143, Unite Mixte Sucrochim, Eridania Beghin Say, F-69603 Villeurbanne, France
[2] Univ Sci & Tech Lille Flandres Artois, CNRS, UMR 111, Chim Biol Lab, F-59655 Villeneuve Dascq, France
关键词：
D O I：
10.1080/07328309808007462
中图分类号：
Q5 [生物化学];
Q7 [分子生物学];
学科分类号：
071010 ;
081704 ;
摘要：
The structure of glucose oligomers obtained by sonochemical glucose polymerization in dodecanol under Fischer glycosylation conditions was investigated. Oligomers having a degree of polymerization up to 23 were observed, with a mean value higher for the sonocatalyzed reaction compared to classical heating, as revealed by mass spectroscopy using the MALDI-TOF technique. The presence of anhydro terminal units was also ascertained by this method. Glycosidic bond types and branching ratios were evaluated after chemical degradation of the oligomers.
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页码：879 / 891
页数：13
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