Synthesis and comparison of polyaniline nanofibers templated by α-, β- and γ-cyclodextrin

被引：21

作者：

Gu, Zhou-Jie ^{[1
]}

Zhang, Qi-Chen ^{[1
]}

Shen, Qing ^{[1
]}

机构：

[1] Donghua Univ, Polymer Dept, State Key Lab Modificat Chem Fiber & Polymer Mat, Shanghai 201620, Peoples R China

来源：

JOURNAL OF POLYMER RESEARCH | 2015年 / 22卷 / 02期

关键词：

Polyaniline; Nanofiber; Cyclodextrin; NANOTUBES;

D O I：

10.1007/s10965-014-0647-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

Three polyaniline, PANI, nanofibers were synthesized with controlled size by using the alpha-, beta -and gamma-cyclodextrin, CD, as template, respectively, via solution polymerization. FESEM images showed that these PANI nanofibers have average diameters, d(a), at about 34, 28 and 32 nm corresponding to the alpha-, beta- and gamma-CD, respectively. The da of PANI nanofibers has been found influenced by the surface properties of those CDs, because there has a good linear relationship betwen da and the Lifshitz-van der Waals interaction component of CDs. FTIR and XRD analyses furthermore explained the reason because the PANI templated by those three CD formed different host-guest inclusion complexes with different crystallinities.

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页数：4

相关论文

共 19 条

[1]

Studies and comparison of the liquid adsorption and surface properties of α-, β- and γ-cyclodextrins by FTIR and capillary rise method [J].

Chen, Lv-Fei ;

Shen, Qing ;

Shen, Ji-Ping ;

Shi, Dong-Ting ;

Chen, Ting ;

Yu, Hao-Ran .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 411 :69-73

[2]

Cyclodextrins: Introduction [J].

D'Souza, VT ;

Lipkowitz, KB .

CHEMICAL REVIEWS, 1998, 98 (05) :1741-1742

[3]

Comparison of polyanilines doped by lignosulfonates with three different ions [J].

Dong, Jin-Qiao ;

Shen, Qing .

JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 126 :E10-E16

[4]

Enhancement in Solubility and Conductivity of Polyaniline with Lignosulfonate Modified Carbon Nanotube [J].

Dong, Jin-Qiao ;

Shen, Qing .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2009, 47 (20) :2036-2046

[5]

Formation of polyaniline nanotubes with different pore shapes using α-, β- and γ-cyclodextrins as templates [J].

Gu, Z. J. ;

Wang, J. T. ;

Li, L. L. ;

Chen, L. F. ;

Shen, Q. .

MATERIALS LETTERS, 2014, 117 :66-68

[6]

Synthesis of polyaniline nanotubes with controlled rectangular or square pore shape [J].

Gu, Z. J. ;

Ye, J. R. ;

Song, W. ;

Shen, Q. .

MATERIALS LETTERS, 2014, 121 :12-14

[7]

Li X, 2007, COLLOIDS SURG PHYSIO, V275, P146

[8]

Stabilizer-free conducting polyaniline nanofiber aqueous colloids and their stability [J].

Li, Xingwei ;

Zhuang, Tao ;

Wang, Gengchao ;

Zhao, Yunpu .

MATERIALS LETTERS, 2008, 62 (8-9) :1431-1434

[9]

Recent advances in synthesis, physical properties and applications of conducting polymer nanotubes and nanofibers [J].

Long, Yun-Ze ;

Li, Meng-Meng ;

Gu, Changzhi ;

Wan, Meixiang ;

Duvail, Jean-Luc ;

Liu, Zongwen ;

Fan, Zhiyong .

PROGRESS IN POLYMER SCIENCE, 2011, 36 (10) :1415-1442

[10]

Synthesis and Characterization of "Hairy Urchin"-like Polyaniline by Using β-Cyclodextrin as a Template [J].

Prasannan, Adhimoorthy ;

Tram Le Bich Truong ;

Hong, Po-Da ;

Somanathan, Narayanasastri ;

Shown, Indrajit ;

Imae, Toyoko .

LANGMUIR, 2011, 27 (02) :766-773