Water dissociation in the presence of metal ions

被引：26

作者：

Coskuner, Orkid ^{[1
]}

Jarvis, Emily A. A. ^{[1
]}

Allison, Thomas C. ^{[1
]}

机构：

[1] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

ab initio calculations; metal ions; molecular dynamics; proton transfer; water chemistry;

D O I：

10.1002/anie.200701617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With or without the metal: Recently, the Grotthuss mechanism of proton transfer in water has been described in detail. A similar mechanism has been found in the vicinity of transition-metal ions, which leads to the formation of Zundel and Eigen complexes (see picture). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7853 / 7855

页数：3

共 30 条

[1] Time-resolved observation of the Eigen cation in liquid water [J].

Amir, Wafa ;

Gallot, Guilhem ;

Hache, Francois ;

Bratos, S. ;

Leicknam, J. -C. ;

Vuilleumier, R. .

JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (03)

[2] Reactions and thermochemistry of small transition metal cluster ions [J].

Armentrout, PB .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2001, 52 :423-461

[3] Ab initio molecular dynamics and quasichemical study of H+(aq) [J].

Asthagiri, D ;

Pratt, LR ;

Kress, JD .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (19) :6704-6708

[4] INFRARED SPECTROSCOPIC EVIDENCE FOR 2ND-SPHERE HYDRATION IN AQUEOUS-SOLUTIONS OF AL-3+, CR-3+, AND RH-3+ [J].

BERGSTROM, PA ;

LINDGREN, J ;

READ, M ;

SANDSTROM, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7650-7655

[5] INTERPRETATION OF X-RAY-DIFFRACTION BY AQUEOUS-SOLUTIONS OF ALUMINUM(III) NITRATE AND CHROMIUM(III) NITRATE [J].

BOL, W ;

WELZEN, T .

CHEMICAL PHYSICS LETTERS, 1977, 49 (01) :189-192

[6] ORDER PHENOMENA IN AQUEOUS ALCL3 SOLUTIONS [J].

CAMINITI, R ;

LICHERI, G ;

PICCALUGA, G ;

PINNA, G ;

RADNAI, T .

JOURNAL OF CHEMICAL PHYSICS, 1979, 71 (06) :2473-2476

[7] THE WATER MOLECULE IN CRYSTALLINE HYDRATES STUDIED BY NEUTRON-DIFFRACTION [J].

CHIARI, G ;

FERRARIS, G .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (SEP) :2331-2341

[8] EVIDENCE FOR THE ROLE OF SOLVATED METAL HYDROXIDE IN THE HAMMERHEAD CLEAVAGE MECHANISM [J].

DAHM, SC ;

DERRICK, WB ;

UHLENBECK, OC .

BIOCHEMISTRY, 1993, 32 (48) :13040-13045

[9] Memoir on the decomposition of water and of the bodies that it holds in solution by means of galvanic electricity [J].

de Grotthuss, C. J. T. .

BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS, 2006, 1757 (08) :871-875

[10] PROTONENUBERTRAGUNG, SAURE-BASE-KATALYSE UND ENZYMATISCHE HYDROLYSE .1. ELEMENTARVORGANGE [J].

EIGEN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1963, 75 (12) :489-&

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