Porous Li4Ti5O12 Coated with N-Doped Carbon from Ionic Liquids for Li-Ion Batteries

被引:756
作者
Zhao, Liang [1 ]
Hu, Yong-Sheng [1 ]
Li, Hong [1 ]
Wang, Zhaoxiang [1 ]
Chen, Liquan [1 ]
机构
[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
关键词
RECHARGEABLE LITHIUM BATTERIES; ELECTRODE PERFORMANCE; SPINEL; ELECTROACTIVITY; LI4+XTI5O12; CAPABILITY; DIFFUSION; INSERTION; LIFEPO4; CELLS;
D O I
10.1002/adma.201003294
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A uniform nitrogen-doped carbon coating layer is formed on Li4Ti5O12 particles by mixing porous Li4Ti5O12 powder with an ionic liquid and then treating the mixture at moderate temperature. Uniformly coated Li4Ti5O12 is shown to have significantly improved rate capability and cycling performance for Li-ion batteries. This relatively simple approach is versatile and can be extended to modify other electrode materials for electrochemical devices.
引用
收藏
页码:1385 / 1388
页数:4
相关论文
共 32 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[3]   Spectroscopic determination of the structure of amorphous nitrogenated carbon films [J].
Bhattacharyya, S ;
Cardinaud, C ;
Turban, G .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (08) :4491-4500
[4]   Size Effects in the Li4+xTi5O12 Spinel [J].
Borghols, W. J. H. ;
Wagemaker, M. ;
Lafont, U. ;
Kelder, E. M. ;
Mulder, F. M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (49) :17786-17792
[5]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[6]   Studies of Mg-substituted Li4-xMgxTi5O12 spinel electrodes (0 ≤ x ≤ 1) for lithium batteries [J].
Chen, CH ;
Vaughey, JT ;
Jansen, AN ;
Dees, DW ;
Kahaian, AJ ;
Goacher, T ;
Thackeray, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :A102-A104
[7]   Carbon-coated Li4Ti5O12 as a high rate electrode material for Li-ion intercalation [J].
Cheng, Liang ;
Li, Xi-Li ;
Liu, Hai-Jing ;
Xiong, Huan-Ming ;
Zhang, Ping-Wei ;
Xia, Yong-Yao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (07) :A692-A697
[8]   STRUCTURE AND ELECTROCHEMISTRY OF THE SPINEL OXIDES LITI2O4 AND LI4/3TI5/3O4 [J].
COLBOW, KM ;
DAHN, JR ;
HAERING, RR .
JOURNAL OF POWER SOURCES, 1989, 26 (3-4) :397-402
[9]   SPINEL ANODES FOR LITHIUM-ION BATTERIES [J].
FERG, E ;
GUMMOW, RJ ;
DEKOCK, A ;
THACKERAY, MM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :L147-L150
[10]   Superior electrode performance of nanostructured mesoporous TiO2 (anatase) through efficient hierarchical mixed conducting networks [J].
Guo, Yu-Guo ;
Hu, Yong-Sheng ;
Sigle, Wilfried ;
Maier, Joachim .
ADVANCED MATERIALS, 2007, 19 (16) :2087-+