Carbon Dioxide Recycling: Emerging Large-Scale Technologies with Industrial Potential

被引:499
作者
Quadrelli, Elsje Alessandra [1 ]
Centi, Gabriele [2 ,3 ]
Duplan, Jean-Luc [4 ]
Perathoner, Siglinda [2 ,3 ]
机构
[1] Univ Lyon 1, Ecole Super Chim Phys Elect Lyon, CPE Lyon, ICL,C2P2,CNRS,UMR LCOMS 5265, F-69616 Villeurbanne, France
[2] Univ Messina, Dipartimento Chim Ind & Ingn Mat, I-98166 Messina, Italy
[3] INSTM CASPE, I-98166 Messina, Italy
[4] IFP Energies Nouvelles, F-69360 Solaize, France
关键词
carbon dioxide; carboxylation; industrial chemistry; reduction; sustainable chemistry; DIMETHYL-ETHER SYNTHESIS; METHANOL SYNTHESIS; VALUABLE PRODUCTS; GREENHOUSE-GAS; POWER-PLANTS; CO2; FIXATION; ACID; PART; CATALYST;
D O I
10.1002/cssc.201100473
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This Review introduces this special issue of ChemSusChem dedicated to CO2 recycling. Its aim is to offer an up-to-date overview of CO2 chemical utilization (inorganic mineralization, organic carboxylation, reduction reactions, and biochemical conversion), as a continuation and extension of earlier books and reviews on this topic, but with a specific focus on large-volume routes and projects/pilot plants that are currently emerging at (pre-) industrial level. The Review also highlights how some of these routes will offer a valuable opportunity to introduce renewable energy into the existing energy and chemical infrastructure (i.e., "drop-in" renewable energy) by synthesis of chemicals from CO2 that are easy to transport and store. CO2 conversion therefore has the potential to become a key pillar of the sustainable and resource-efficient production of chemicals and energy from renewables.
引用
收藏
页码:1194 / 1215
页数:22
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