Neutral nickel(II)-based catalysts for ethylene polymerization

被引：661

作者：

Wang, CM

Friedrich, S

Younkin, TR

Li, RT

Grubbs, RH ^{[1
]}

Bansleben, DA

Day, MW

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synthesis, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[2] Sealed Air Corp, Cryovac Div, Columbia, MD 21044 USA

[3] CALTECH, Beckman Inst, Crystallog Lab, Pasadena, CA 91125 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 15期

关键词：

D O I：

10.1021/om980176y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Neutral salicylaldiminato Ni(II) complexes have been, synthesized, and their structure has been confirmed by an X-ray analysis of complex: 4e. These compounds are active catalysts for the polymerization of ethylene under mild conditions in the presence of a phosphine scavenger such as Ni(COD)(2) or B(C6F5)(3).

引用

收藏

页码：3149 / 3151

页数：3

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