RUTHENIUM(II) COMPLEXES OF O,N-DONOR SCHIFF-BASE LIGANDS AND THEIR USE AS CATALYTIC ORGANIC OXIDANTS

被引：100

作者：

ELHENDAWY, AM ^{[1
]}

ALKUBAISI, AH ^{[1
]}

ELKOURASHY, AE ^{[1
]}

SHANAB, MM ^{[1
]}

机构：

[1] FAC SCI DAMIETTA,DEPT CHEM,DAMIETTA,EGYPT

来源：

POLYHEDRON | 1993年 / 12卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83051-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of new ruthenium(II) complexes, [Ru(PPh3)2L2] (L = monoanions of Schiff bases formed from 2,3-dihydroxybenzaldehyde, 3,5-dibromosalicylaldehyde and salicylaldehyde with aniline or its p-substituents), have been prepared. They were characterized by spectroscopic techniques and investigated by cyclic voltammetry. The effective catalytic oxidation of alcohols by these complexes in the presence of N-methylmorpholine-N-oxide or molecular oxygen gas as co-oxidants is reported.

引用

页码：2343 / 2350

页数：8

共 42 条

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