A quadruply stranded metallohelicate and its spontaneous dimerization into an interlocked metallohelicate

被引：158

作者：

Fukuda, Morihiko ^{[2
]}

Sekiya, Ryo ^{[1
]}

Kuroda, Reiko ^{[1
,2
,3
]}

机构：

[1] Univ Tokyo, Dept Life Sci, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

[2] Univ Tokyo, Grad Sch Sci, Dept Biophys & Biochem, Bunkyo Ku, Tokyo 1130033, Japan

[3] ERATO SORST, Japan Sci & Technol Agcy, Kuroda Chiromorphol Team, Tokyo 1530041, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 04期

关键词：

cage compounds; helical structures; interlocked structures; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200703162

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Making up a foursome: Self-assembly of 4,4′-(3-pyridinemethoxy)benzophenone (L) and Pd(NO3) 2 resulted in the quantitative formation of a quadruply stranded metallohelicate [Pd2(L)4], which undergoes spontaneous dimerization to an unprecedented chiral interlocked metallohelicate [Pd 2(L)4]2 (see X-ray structure; C black, H white, N blue, O red). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：706 / 710

页数：5

共 34 条

[1] Host-guest interactions: Design strategy and structure of an unusual cobalt cage that encapsulates a tetrafluoroborate anion [J].

Amouri, H ;

Mimassi, L ;

Rager, MN ;

Mann, BE ;

Guyard-Duhayon, C ;

Raehm, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (29) :4543-4546

[2]

AMOURI H, 2005, ANGEW CHEM, V117, P4619

[3]

[Anonymous], 1998, ANGEW CHEM, V110, P3495

[4] An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].

Barbour, LJ ;

Orr, GW ;

Atwood, JL .

NATURE, 1998, 393 (6686) :671-673

[5]

BURLA MC, SIR 2004 PROGRAM AUT

[6] Spontaneous assembly of ten components into two interlocked, identical coordination cages [J].

Fujita, M ;

Fujita, N ;

Ogura, K ;

Yamaguchi, K .

NATURE, 1999, 400 (6739) :52-55

[7] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[8]

Gregolinski J., 2006, ANGEW CHEM, V118, P6268, DOI DOI 10.1002/ANGE.200602464

[9] Helicity inversion in lanthanide(III) complexes with chiral nonaaza macrocyclic ligands [J].

Gregolinski, Janusz ;

Lisowski, Jerzy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (37) :6122-6126

[10] Self-assembly mechanism of a bimetallic europium triple-stranded helicate [J].

Hamacek, J ;

Blanc, S ;

Elhabiri, M ;

Leize, E ;

Van Dorsselaer, A ;

Piguet, C ;

Albrecht-Gary, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (06) :1541-1550

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