Novel stable metallic salts based on a donor molecule containing peri-ditellurium bridges, TMTTeN

被引：15

作者：

Arai, E

Fujiwara, H

Kobayashi, H

Kobayashi, A ^{[1
]}

Takimiya, K

Otsubo, T

Ogura, F

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 113, Japan

[2] Inst Mol Sci, Okazaki, Aichi 444, Japan

[3] Grad Univ Adv Studies, Sch Math & Phys Sci, Okazaki, Aichi 444, Japan

[4] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 739, Japan

[5] Kinki Univ, Fac Engn, Dept Ind Chem, Higashihiroshima 73921, Japan

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 12期

关键词：

D O I：

10.1021/ic9802247

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first stable organic metals of the peri-ditellurium-bridged polyacene donor TMTTeN were obtained as TMTTeN2M(CN)(2) (M = Ag, Au). Crystal structure analyses revealed three-dimensional networks through intermolecular Te ... Te contacts. The salts are highly conductive (500-1000 S cm(-1)) and keep the metallic states down to low temperature. The extended Huckel tight-binding band calculation gave the quasi-three-dimensional Fermi surfaces.

引用

页码：2850 / 2851

页数：2

共 18 条

[1]

COWAN D, 1987, CHEM ORGANIC SELENIU, V2, P463

[2] STRUCTURAL AND ELECTRONIC-PROPERTIES OF TSF-TCNQ, TSEF-TCNQ,TTEF-TCNQ [J].