Photolithographically patterned smart hydrogel based bilayer actuators

被引:210
作者
Bassik, Noy [1 ,2 ]
Abebe, Beza T. [3 ]
Laflin, Kate E. [1 ]
Gracias, David H. [1 ,4 ]
机构
[1] Johns Hopkins Univ, Dept Chem & Biomol Engn, Baltimore, MD 21218 USA
[2] Johns Hopkins Univ, Sch Med, Baltimore, MD 21205 USA
[3] Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA
[4] Johns Hopkins Univ, Dept Chem, Baltimore, MD 21218 USA
关键词
Hydrogel; Smart polymer; Actuator; N-ISOPROPYLACRYLAMIDE; IONIC-STRENGTH; GELS; MICROSTRUCTURES; MICROGRIPPERS; TEMPERATURE; PARTICLES; DIFFUSION; MICROGELS; MODELS;
D O I
10.1016/j.polymer.2010.10.035
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We describe the fabrication of photopatterned actuators, composed of stimuli-responsive hydrogel bilayers made from N-isopropyl-acrylamide (NIPAm), acrylic acid (AAc), and poly-ethylene oxide diacrylate (PEODA). The hydrogels were deposited by spin coating and casting and were patterned by non-contact photolithography. We investigated the swelling behavior of the individual photopatterned hydrogels in aqueous solutions of varying pH and ionic strength (IS). By combining materials with optimal swelling responses, bilayer structures were triggered via changes in pH and IS to actuate into three dimensional (3D) structures. We also used these hydrogel bilayers as hinges to actuate integrated structures composed of rigid polymeric SU-8 panels, patterned to resemble the shape of a Venus Flytrap. This system provides a straightforward way to design and fabricate actuator hinges composed entirely of polymers. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6093 / 6098
页数:6
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