Electrochemical nanostructuring with ultrashort voltage pulses

被引:54
作者
Kirchner, V [1 ]
Xia, XH [1 ]
Schuster, R [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
D O I
10.1021/ar000133p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The application of nanosecond voltage pulses to electrodes provides three ways to conduct local electrochemistry on the micro- to nanometer scale. (1) The finite charging time of the double-layer capacity allows the machining of three-dimensional microstructures. (2) In an electrochemical scanning tunneling microscope, reactions are confined to the tunneling region, due to the depletion of the electrolyte in the tip-surface gap. (3) Ordering processes, following very fast electrochemical reactions, lead to unconventional island patterns on a surface.
引用
收藏
页码:371 / 377
页数:7
相关论文
共 35 条
[1]  
Andricacos P. C., 1999, Electrochemical Society Interface, V8, P32
[2]   Atomic force microscope tip-induced local oxidation of silicon: Kinetics, mechanism, and nanofabrication [J].
Avouris, P ;
Hertel, T ;
Martel, R .
APPLIED PHYSICS LETTERS, 1997, 71 (02) :285-287
[3]  
Bard A.J., 1994, ELECTROANAL CHEM, V18, A., P243
[4]   SCANNING ELECTROCHEMICAL MICROSCOPY - A NEW TECHNIQUE FOR THE CHARACTERIZATION AND MODIFICATION OF SURFACES [J].
BARD, AJ ;
DENUAULT, G ;
LEE, C ;
MANDLER, D ;
WIPF, DO .
ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (11) :357-363
[5]  
Bell G. M., 1989, STAT MECH LATTICE MO
[6]   THEORY OF 1ST-ORDER PHASE-TRANSITIONS [J].
BINDER, K .
REPORTS ON PROGRESS IN PHYSICS, 1987, 50 (07) :783-859
[7]  
Bockris J. OM., 1970, Modern electrochemistry: an introduction to an interdisciplinary area [by], V2
[8]  
Boudart M., 2014, KINETICS HETEROGENEO
[9]  
Brune H, 1998, SURF SCI REP, V31, P121, DOI 10.1016/S0167-5729(99)80001-6
[10]   QUANTUM CRYSTALLITES AND NONLINEAR OPTICS [J].
BRUS, L .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1991, 53 (06) :465-474