Electrochemical nanostructuring with ultrashort voltage pulses

被引:54
作者
Kirchner, V [1 ]
Xia, XH [1 ]
Schuster, R [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
D O I
10.1021/ar000133p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The application of nanosecond voltage pulses to electrodes provides three ways to conduct local electrochemistry on the micro- to nanometer scale. (1) The finite charging time of the double-layer capacity allows the machining of three-dimensional microstructures. (2) In an electrochemical scanning tunneling microscope, reactions are confined to the tunneling region, due to the depletion of the electrolyte in the tip-surface gap. (3) Ordering processes, following very fast electrochemical reactions, lead to unconventional island patterns on a surface.
引用
收藏
页码:371 / 377
页数:7
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