Synthesis of 7-hydroxycoumarins by Pechmann reaction using Nafion resin/silica nanocomposites as catalysts

被引：103

作者：

Laufer, MC ^{[1
]}

Hausmann, H ^{[1
]}

Hölderich, W ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, RWTH Aachen, Dept Chem Technol & Heterogeneous Catalysis, D-52074 Aachen, Germany

来源：

JOURNAL OF CATALYSIS | 2003年 / 218卷 / 02期

关键词：

Pechmann reaction; solid acid catalyst; Nafion resin/silica nanocomposite; coumarin derivatives;

D O I：

10.1016/S0021-9517(03)00073-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of resorcinol with ethyl acetoacetate (Pechmann reaction) or with acrylic acid over novel Nafion resin/silica composite materials with 40 and 80 wt% of Nafion in silica produces 7-hydroxycoumarins in high yields, under mild reaction conditions in short reaction time. Other solid acid catalysts were tested for comparison reasons. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：315 / 320

页数：6