A new practical asymmetric synthesis of C-2-symmetrical 1,1'-ferrocenyl diols via CBS-reduction

被引：64

作者：

Schwink, L ^{[1
]}

Knochel, P ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 01期

关键词：

D O I：

10.1016/0040-4039(95)02098-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

CBS-reduction of ferrocenyl diketones 3 provides C-2-symmetrical ferrocenyl diols (R,R)-1 in > 98% ee accompanied by small amounts of the meso-diols (R,S)-1. The utility of 1 for the preparation of various potential ligands for asymmetric catalysis such as 9, 12, 13 and 14 is demonstrated.

引用

页码：25 / 28

页数：4

共 26 条

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