Fabrication of nanocrystalline ZnWO4 with different morphologies and sizes via hydrothermal route

被引:93
作者
Chen, SJ
Zhou, JH
Chen, XT
Li, J
Li, LH
Hong, JM
Xue, ZL
You, XZ
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Analyt Ctr, Nanjing 210093, Peoples R China
[4] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(03)00878-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
ZnWO4 nanocrystals have been prepared via a hydrothermal route, and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy. The size and morphology of ZnWO4 nanocrystals were found to depend on the reaction temperature and pH. The length of ZnWO4 nanorod increased with the increase in pH of the hydrothermal solution. An unusual nanoparticle-to-nanorod transformation was observed during the formation of ZnWO4 nanoparticles at pH 11.0 and 180 degreesC. Luminescent properties Of ZnWO4 nanocrystals were investigated by photoluminescence (PL) spectroscopy. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:185 / 190
页数:6
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