The strength of the macromonomer strategy for complex macromolecular architecture: Molecular characterization, properties and applications of polymacromonomers

被引：199

作者：

Hadjichristidis, N ^{[1
]}

Pitsikalis, M ^{[1
]}

Iatrou, H ^{[1
]}

Pispas, S ^{[1
]}

机构：

[1] Univ Athens, Dept Chem, GR-15771 Athens, Greece

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 17期

关键词：

macromolecular architectures; macromonomers; potential applications; properties; synthesis;

D O I：

10.1002/marc.200300050

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The efficiency of the macromonomer (MM) synthetic strategy for the creation of nonlinear complex macromolecular architectures (miktoarm stars, alpha,omega-branched polymers, random/exact comb and graft copolymers, dendritic polymers, molecular brushes) is reviewed. In addition, the solution/bulk properties and the potential applications of polymacromonomers (PMM), as well as new synthetic ideas are presented. The synthesis of macromonomers and living polymacromonomers in situ leads to many novel linear and nonlinear structures, as for example PMM-b-PS-b-PMM, (PS)(2)PMM. The use of multichlorosilylstyrenes as <LF>monomer/linking agents opens new ways for structures with multichain macromonomeric building blocks.

引用

页码：979 / 1013

页数：35

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[41] Copper(I)-mediated living radical polymerization in the presence of oxyethylene groups:: Online 1H NMR spectroscopy to investigate solvent effects [J].