Sustainable metal catalysis with iron: From rust to a rising star?

被引:1062
作者
Enthaler, Stephan [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany
关键词
coupling reactions; homogeneous catalysis; iron; oxidation; reduction;
D O I
10.1002/anie.200800012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Among the shades! With respect to its availability, low toxicity, and price, iron should be one of the most used metals in homogeneous catalysis. Surprisingly, so far the application of iron is underdeveloped in comparison with other transition metals. Some promising attempts obtained in redox reactions and coupling chemistry which nicely illustrate the potential of iron and hopefully initialize a ferric future for catalysis are highlighted. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3317 / 3321
页数:5
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