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An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide

被引：123
作者：
Anilkumar, Gopinathan
Bitterlich, Bianca
Gelalcha, Feyissa Gadissa
Tse, Man Kin
Beller, Matthias
机构：
[1] Leibniz Inst Katalyse, D-18059 Rostock, Germany
[2] Ctr Life Sci Automat, D-18119 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 03期
关键词：
D O I：
10.1039/b612048b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new, environmentally benign and practical epoxidation method was developed using inexpensive and efficient Fe catalysts. FeCl3 center dot 6H(2)O in combination with commercially available pyridine-2,6-dicarboxylic acid and amines showed excellent reactivity and selectivity towards aromatic olefins and moderate reactivity towards 1,3-cyclooctadiene utilizing H2O2 as the terminal oxidant.
引用
收藏
页码：289 / 291
页数：3
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