An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide

被引：123

作者：

Anilkumar, Gopinathan

Bitterlich, Bianca

Gelalcha, Feyissa Gadissa

Tse, Man Kin

Beller, Matthias

机构：

[1] Leibniz Inst Katalyse, D-18059 Rostock, Germany

[2] Ctr Life Sci Automat, D-18119 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 03期

关键词：

D O I：

10.1039/b612048b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new, environmentally benign and practical epoxidation method was developed using inexpensive and efficient Fe catalysts. FeCl3 center dot 6H(2)O in combination with commercially available pyridine-2,6-dicarboxylic acid and amines showed excellent reactivity and selectivity towards aromatic olefins and moderate reactivity towards 1,3-cyclooctadiene utilizing H2O2 as the terminal oxidant.

引用

页码：289 / 291

页数：3

共 53 条

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