Tandem modification of metal-organic frameworks by a postsynthetic approach

被引：172

作者：

Wang, Zhenqiang ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 25期

关键词：

metals; organic-inorganic hybrid composites; polymers; supramolecular chemistry; zinc;

D O I：

10.1002/anie.200800686

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) More than a one-trick pony: Postsynthetic modification of metal-organic frameworks (MOFs) permits stepwise, "tandem" modification of the lattice. An MOF bearing reactive functional groups can be subjected to a controllable, heterogeneous transformation sequence while retaining its structural integrity and microporosity. This approach allows the synthesis of MOFs bearing multiple functional groups (represented in the scheme by green and pink spheres). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4699 / 4702

页数：4

共 21 条

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