N-confused and N-fused meso-aryl sapphyrins

被引：65

作者：

Gupta, Iti ^{[1
]}

Srinivasan, Alagar ^{[1
]}

Morimoto, Tatsuki ^{[1
]}

Toganoh, Motoki ^{[1
]}

Furuta, Hiroyuki ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8190395, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 24期

关键词：

fused-ring systems; porphyrinoids; rhenium; sapphyrins;

D O I：

10.1002/anie.200705984

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Presented) A state of (con)fusion: The introduction of a confused pyrrole ring into a meso-aryl sapphyrin framework destabilizes the macrocycle and forces a fusion reaction to occur. Subsequent metalation with rhenium results in further mutation to form a domino-fused sapphyrin with a fused penta-ring system (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4563 / 4567

页数：5

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