Reductive disproportionation of carbon dioxide at an iron(II) center

被引：37

作者：

Allen, Olivia R. ^{[1
]}

Dalgarno, Scott J. ^{[2
]}

Field, Leslie D. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 14期

关键词：

D O I：

10.1021/om800408w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cis-Fe(dmpe)(2)H-2 (1) with C-13-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)(2)(CO)H]center dot[HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation Of CO2 to CO and CO32-. trans-[Fe(dmpe)(2)(CO)H]center dot[HCO3] (5) was characterized by crystallography and by NMR spectroscopy.

引用

页码：3328 / 3330

页数：3

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