Reductive disproportionation of carbon dioxide at an iron(II) center

被引：37

作者：

Allen, Olivia R. ^{[1
]}

Dalgarno, Scott J. ^{[2
]}

Field, Leslie D. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 14期

关键词：

D O I：

10.1021/om800408w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of cis-Fe(dmpe)(2)H-2 (1) with C-13-labeled carbon dioxide (CO2) was investigated, and trans[Fe(dmpe)(2)(CO)H]center dot[HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation Of CO2 to CO and CO32-. trans-[Fe(dmpe)(2)(CO)H]center dot[HCO3] (5) was characterized by crystallography and by NMR spectroscopy.

引用

页码：3328 / 3330

页数：3

共 30 条

[21]

HILLS A, 1993, DALTON T, P3041

[22] FUNCTIONAL DERIVATIVES OF TRIMETHYLPHOSPHINE .3. AMBIVALENT BEHAVIOR OF TETRAKIS(TRIMETHYLPHOSPHINE)IRON - REACTION WITH CO2 [J].

KARSCH, HH .

CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (06) :2213-2221

[23] TRANSITION-METAL-SILYL COMPLEXES .25. SILYL-SUBSTITUTED TRIHYDRIDO IRON COMPLEXES, FEH3(CO)(DPPE)SIR3 (DPPE=PH2PCH2CH2PPH2) [J].

KNORR, M ;

GILBERT, S ;

SCHUBERT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 347 (03) :C17-C20

[24] TRANSITION-METAL SILYL COMPLEXES .18. HYDRIDO-SILYL AND BISSILYL COMPLEXES OF IRON WITH BRIDGING OR CHELATING DIPHOSPHINOETHANE LIGANDS [J].

KNORR, M ;

MULLER, J ;

SCHUBERT, U .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (06) :879-887

[25] Acidic dicationic iron(II) dihydrogen complexes and compounds related by H2 substitution [J].

Landau, SE ;

Morris, RH ;

Lough, AJ .

INORGANIC CHEMISTRY, 1999, 38 (26) :6060-6068

[26] REDUCTIVE DISPROPORTIONATION OF CARBON-DIOXIDE BY DIANIONIC CARBONYLMETALATES OF THE TRANSITION-METALS [J].

LEE, GR ;

MAHER, JM ;

COOPER, NJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (10) :2956-2962

[27] The coordination chemistry of carbon dioxide and its relevance for catalysis: A critical survey [J].

Leitner, W .

COORDINATION CHEMISTRY REVIEWS, 1996, 153 :257-284

[28] Transition metal catalyzed reactions of carbon dioxide and other heterocumulenes [J].

Louie, J .

CURRENT ORGANIC CHEMISTRY, 2005, 9 (07) :605-623

[29] Aspects of carbon dioxide utilization [J].

Omae, Iwao .

CATALYSIS TODAY, 2006, 115 (1-4) :33-52

[30] Reduction of CO2 to CO using low-coordinate iron:: Formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex [J].

Sadique, Azwana R. ;

Brennessel, William W. ;

Holland, Patrick L. .

INORGANIC CHEMISTRY, 2008, 47 (03) :784-786

← 1 2 3 →