Unusual complexes formed by the early lanthanides with 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines

被引：54

作者：

Drew, MGB ^{[1
]}

Guillaneux, D

Hudson, MJ

Iveson, PB

Madic, C

机构：

[1] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

[2] CEA, Valrho, DEN, DRCP,SCPS,LCAM, Bagnols Sur Ceze, France

[3] CEA Saclay, DEN, F-91191 Gif Sur Yvette, France

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

lanthanides; actinides; extraction; nuclear reprocessing;

D O I：

10.1016/S1387-7003(01)00210-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of lanthanide(III) nitrates (La-Sm) to the actinide(III) extracting agents, 2,6-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-pyridines in a 1:1 ratio, results in the crystallisation of unusual dimeric complexes [Ln(2)(L-1)(2)(NO3)(6)] as well as more usual mononuclear complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：462 / 466

页数：5

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