Highly stable Gold(III) complex with a hydantoin ligand in alkaline media

被引：35

作者：

Oyaizu, K

Ohtani, Y

Shiozawa, A

Sugawara, K

Saito, T

Yuasa, M ^{[1
]}

机构：

[1] Tokyo Univ Sci, Inst Colloid & Interface Sci, Tokyo 1628601, Japan

[2] Univ Tokyo, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan

[3] Tanaka Kikinzoku Kogyo KK, Hiratsuka, Kanagawa 2540076, Japan

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 20期

关键词：

D O I：

10.1021/ic050515x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)(4)](-), is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

引用

页码：6915 / 6917

页数：3

共 25 条

[21] THE AUTOCATALYTIC DEPOSITION OF GOLD IN NONALKALINE, GOLD THIOSULFATE ELECTROLESS BATH [J].