Contact conditions for the charge in the theory of the electrical double layer

被引：36

作者：

Holovko, M

Badiali, JP

di Caprio, D

机构：

[1] Natl Acad Sci, Inst Condensed Matter Phys, UA-79011 Lvov, Ukraine

[2] Univ Paris 06, Lab Electrochim & Chim Analyt, Unite Mixte Rech 7575, F-75230 Paris 05, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 23期

关键词：

D O I：

10.1063/1.2137707

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, from the Born-Green-Yvon equations of the liquid-state theory, we derive a general expression for the charge-density contact value at charged interfaces. This relation is discussed, in particular, for symmetrical electrolytes. We emphasize an essential coupling between the electric properties and the density profile. Limiting behavior at small and large charges at the interface is discussed.

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页数：5

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