Tris(1,10-phenanthroline)ruthenium(II) bis(hexafluorophosphate)

被引：46

作者：

Breu, J

Stoll, AJ

机构：

[1] Inst. für Anorganische Chemie, Universität Regensburg

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195017057

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ru(phen)(3)](PF6)(2) (phen = 1, 10-phenanthroline), [Ru(C12H8N2)(3)](PF6)(2), is homostructural with the perchlorate monohydrates of the Cu-II, Co-II, Os-II and Fe-II analogues. This homomorphism is notable in view of the widely differing metal-atom environments and counterion sizes, and suggests that the packing arrangement is a general and accomodating one among tris(1,10-phenanthroline)metal(II) complexes. While [Ru(bpy)(3)](PF6)(2) is built up from homochiral layers, [Ru(phen)(3)](PF6)(2) is composed of rigorously racemic layers of complex cations parallel to the bc plane, with counterions sandwiched between. The average length of the Ru-N bonds [2.063 (4) Angstrom] and the average ligand bite angle [79.8 (2)degrees] compare well with the values published for [Ru(bpy)(3)](PF6)(2) [2.056 (2) Angstrom and 78.7 (1)degrees, respectively].

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页码：1174 / 1177

页数：4

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