Borylene metathesis through [2+2] cycloaddition

被引：49

作者：

Braunschweig, Holger ^{[1
]}

Burder, Michael ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Seeler, Fabian ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 42期

关键词：

boron; borylene complexes; manganese; metathesis;

D O I：

10.1002/anie.200702982

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) From Mn=B to Mn=C: The first example of a concerted borylene metathesis through a clean cycloaddition-cycloreversion sequence is established, emphasizing the decisive influence of boron-bound substituents, and alkyl groups in particular, on the reactivity of borylene complexes. Cyclic reaction intermediates were characterized by X-ray diffraction analysis. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8071 / 8073

页数：3

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