Transition metal boryl and borylene complexes: substitution and abstraction chemistry

被引：278

作者：

Aldridge, S ^{[1
]}

Coombs, DL ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 7-8期

基金：

英国工程与自然科学研究理事会;

关键词：

boryl; borylene; diboran(4)yl; boron; transition metal; substitution; abstraction; halide;

D O I：

10.1016/j.ccr.2003.12.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this article, an account is given of recent developments in the chemistry of transition metal complexes of boron. Particular emphasis has been placed on the fundamental reaction chemistry of these systems which leaves the metal-boron bond(s) (M-B) intact. Substitution and abstraction chemistries have been developed in recent years and exploited to give access to a number of novel ligand types. This article summarizes these advances in a previously little investigated area of boryl/borylene chemistry. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：535 / 559

页数：25

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