Transition metal boryl and borylene complexes: substitution and abstraction chemistry

被引：278

作者：

Aldridge, S ^{[1
]}

Coombs, DL ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 7-8期

基金：

英国工程与自然科学研究理事会;

关键词：

boryl; borylene; diboran(4)yl; boron; transition metal; substitution; abstraction; halide;

D O I：

10.1016/j.ccr.2003.12.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this article, an account is given of recent developments in the chemistry of transition metal complexes of boron. Particular emphasis has been placed on the fundamental reaction chemistry of these systems which leaves the metal-boron bond(s) (M-B) intact. Substitution and abstraction chemistries have been developed in recent years and exploited to give access to a number of novel ligand types. This article summarizes these advances in a previously little investigated area of boryl/borylene chemistry. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：535 / 559

页数：25

共 134 条

[91] REDOX-ACTIVE ORGANOMETALLIC IR COMPLEXES CONTAINING BIPHENYL-2,2'-DIYL [J].

LU, Z ;

JUN, CH ;

DEGALA, SR ;

SIGALAS, M ;

EISENSTEIN, O ;

CRABTREE, RH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (24) :1877-1880

[92] A theoretical study of free and Fe(CO)4-complexed borylenes (boranediyls) and heavier congeners:: The nature of the iron-group 13 element bonding [J].

Macdonald, CLB ;

Cowley, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (51) :12113-12126

[93] C-H activation/borylation/oxidation: A one-pot unified route to meta-substituted phenois bearing ortho-/para-directing groups [J].

Maleczka, RE ;

Shi, F ;

Holmes, D ;

Smith, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) :7792-7793

[94] SYNTHESIS AND REACTIVITY OF SILICON-TRANSITION METAL-COMPLEXES .13. BINUCLEAR IRON COMPLEXES CONTAINING UNSYMMETRICALLY SUBSTITUTED SILANEDIYL BRIDGES [J].

MALISCH, W ;

RIES, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1978, 17 (02) :120-121

[95] CATALYTIC HYDROBORATION WITH RHODIUM COMPLEXES [J].

MANNIG, D ;

NOTH, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (10) :878-879

[96] Transition metal catalysed diboration [J].

Marder, TB ;

Norman, NC .

TOPICS IN CATALYSIS, 1998, 5 (1-4) :63-73

[97] DIRECT OBSERVATION OF ION-PAIR FORMATION IN DICHLOROMETHANE SOLUTION AND THE CRYSTAL-STRUCTURE OF [(ETA-5-C5ME5)FE(CO)3][BF4] [J].

MCARDLE, P ;

MACHALE, D ;

CUNNINGHAM, D ;

MANNING, AR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 419 (1-2) :C18-C20

[98] SYNTHESIS AND STRUCTURES OF THE 1ST TRANSITION-METAL TRIS(BORYL) COMPLEXES - (ETA-6-ARENE)IR(BO2C6H4)3 [J].

NGUYEN, P ;

BLOM, HP ;

WESTCOTT, SA ;

TAYLOR, NJ ;

MARDER, TB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) :9329-9330

[99] ONE-ELECTRON REDUCTION OF THE IRON CARBENE COMPLEXES [FE(CP-ASTERISK)(CO)2(=C(OME)R)]+ (R = H OR ME) AND HYDROGEN-ATOM VS ALKYL-RADICAL TRANSFER IN THE 19-ELECTRON INTERMEDIATES [J].

NLATE, S ;

GUERCHAIS, V ;

LAPINTE, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 434 (01) :89-96

[100] METALL-BOR-VERBINDUNGEN .1. BIS(DIMETHYLAMINO)BOR-MANGANCARBONYL UND EINIGE SEINER DERIVATE [J].

NOTH, H ;

SCHMID, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 5 (02) :109-&

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