New titanium complexes having two indolide-imine chelate ligands for living ethylene polymerization

被引：63

作者：

Matsugi, T ^{[1
]}

Matsui, S ^{[1
]}

Kojoh, S ^{[1
]}

Takagi, Y ^{[1
]}

Inoue, Y ^{[1
]}

Fujita, T ^{[1
]}

Kashiwa, N ^{[1
]}

机构：

[1] Mitsui Chem Inc, R&D Ctr, Sodegaura, Chiba 2990265, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 06期

关键词：

D O I：

10.1246/cl.2001.566

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three new titanium complexes having two indolide-imine ligands were synthesized and investigated as ethylene polymerization catalysts. These complexes using MAO as a cocatalyst promoted ethylene polymerization at 25 degreesC to produce polyethylenes (M-n:11000-41800) having narrow molecular weight distributions (M-w/M-n: 1.11-1.14, displaying very high activities (52-288 kg-PE/mol-Ti(.)h(.)atm).

引用

页码：566 / 567

页数：2

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