Synthesis of a jojoba bean disaccharide

被引：16

作者：

Kornienko, A ^{[1
]}

Marnera, G ^{[1
]}

d'Alarcao, M ^{[1
]}

机构：

[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA

来源：

CARBOHYDRATE RESEARCH | 1998年 / 310卷 / 1-2期

基金：

美国国家卫生研究院;

关键词：

chiro-inositol; jojoba beans; glycosylation; synthesis; samarium diiodide;

D O I：

10.1016/S0008-6215(98)00168-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

A synthesis of the disaccharide recently isolated from jojoba beans, 2-O-alpha-D-galactopyranosyl-D-chiro-inositol, has been achieved. The suitably protected chiro-inositol unit was prepared by an enantiospecific synthesis from L-xylose utilizing SmI2-mediated pinacol coupling as a key step. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：141 / 144

页数：4

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