Ruthenium catalyzed asymmetric transfer hydrogenation of β-ketoesters

被引：34

作者：

Everaere, K

Carpentier, JF

Mortreux, A

Bulliard, M

机构：

[1] ENSCL, CNRS, Catalyse Heterogene & Homogene Lab, F-59652 Villeneuve Dascq, France

[2] SIPSY, PPG, F-49242 Avrille, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 17期

关键词：

D O I：

10.1016/S0957-4166(98)00325-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chemoselective transfer hydrogenation of beta-ketoesters to the corresponding alcohols is achieved in the presence of catalytic combinations of [RuCl2(eta(6)-arene)](2) and ephedrine or diamino type chiral ligands with activities up to 190 h(-1) at 20 degrees C and moderate to good enantiomeric excesses ranging from 36 to 94%. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2971 / 2974

页数：4

共 9 条

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