In situ fluorescent labeling of highly volatile methylamine with 8-(4,6-dichloro-1,3,5-triazinoxy)quinoline

被引:27
作者
Ma, HM [1 ]
Jarzak, U
Thiemann, W
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Univ Bremen, Dept Chem, D-28334 Bremen, Germany
关键词
D O I
10.1039/b101711j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first in situ fluorescent labeling probe for monitoring of highly volatile methylamine, 8-(4,6-dichloro-1,3,5-triazinoxy)quinoline, has been designed, synthesized and evaluated. The probe labels spectroscopically inert methylamine, causing a large change in fluorescence properties through suppression of the internal charge transfer, and thus can serve as an in situ labeling probe. This applicability has been demonstrated by measuring methylamine released during hydrolysis of N-methylcarbamates such as ethiofencarb.
引用
收藏
页码:872 / 874
页数:3
相关论文
共 22 条
[21]   Design principles of fluorescent molecular sensors for cation recognition [J].
Valeur, B ;
Leray, I .
COORDINATION CHEMISTRY REVIEWS, 2000, 205 :3-40
[22]  
ZOLLINGER H, 1991, COLOR CHEM, P11