A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

被引：80

作者：

Reinsch, Helge ^{[1
]}

Marszalek, Bartosz ^{[2
]}

Wack, Julia ^{[3
]}

Senker, Juergen ^{[3
]}

Gil, Barbara ^{[2
]}

Stock, Norbert ^{[1
]}

机构：

[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany

[2] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

[3] Univ Bayreuth, D-95447 Bayreuth, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 76期

关键词：

METAL-ORGANIC-FRAMEWORK; MIL-101;

D O I：

10.1039/c2cc34909d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new Al-based metal-organic framework [Al-13(OH)(27)(H2O)(6)-(BDC-NH2)(3)Cl-6(C3H7OH)(6)] denoted CAU-6 (CAU = Christian-Albrechts-Universitat) was solvothermally synthesized in 2-propanol and was thoroughly characterized. The framework structure exhibits a unique column-shaped inorganic building unit, which is based on stacked, corner-sharing Al-13-clusters. The compound exhibits unprecedented hydrophilicity for metal-organic frameworks.

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页码：9486 / 9488

页数：3

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