[Al4(OH)2(OCH3)4(H2N-bdc)3]•xH2O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick

被引：259

作者：

Ahnfeldt, Tim ^{[1
]}

Guillou, Nathalie ^{[2
]}

Gunzelmann, Daniel ^{[3
]}

Margiolaki, Irene ^{[4
]}

Loiseau, Thierry ^{[2
]}

Ferey, Gerard ^{[2
]}

Senker, Juergen ^{[3
]}

Stock, Norbert ^{[1
]}

机构：

[1] Univ Kiel, Inst Anorgan Chem, D-24118 Kiel, Germany

[2] Univ Versailles St Quentin, CNRS, UMR 8637, Inst Lavoisier, F-78035 Versailles, France

[3] Univ Bayreuth, D-95447 Bayreuth, Germany

[4] European Synchrotron Radiat Facil, Mat Sci Grp ID31, F-38043 Grenoble, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 28期

关键词：

organic-inorganic hybrid composites; high-throughput methods; metal-organic frameworks; microporous materials; solvothermal synthesis; HIGH-THROUGHPUT SYNTHESIS; COORDINATION POLYMER; CRYSTAL-STRUCTURE; HYBRID COMPOUNDS; TOPOLOGY; MIL-53; TEMPERATURE; CLUSTERS; PROGRAM; SOLIDS;

D O I：

10.1002/anie.200901409

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12-connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5163 / 5166

页数：4

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