First example of double bond migration in the electrochemical CO2 incorporation into (perfluoroalkyl)alkenes

被引：12

作者：

Chiozza, E

Desigaud, M

Greiner, J

Duñach, E

机构：

[1] Univ Nice, Lab Chim Mol, CNRS, F-06108 Nice 2, France

[2] Univ Nice, Chim Bioorgan Lab, CNRS, F-06108 Nice, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 27期

关键词：

carboxylation; electrochemical reactions; olefins; perfluoroalkyl compounds;

D O I：

10.1016/S0040-4039(98)00948-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical, nickel-catalyzed addition of CO2 to (perfluoroalkyl)alkenes leads to gamma-fluoro-gamma-(perfluoroalkyl)-beta-alkenyl carboxylic acids, involving a double bond migration with loss of one fluorine atom. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4831 / 4834

页数：4

共 25 条

[1] SYNTHESIS OF 2H,2H-PERFLUOROALKYL AND 2H-PERFLUOROALKENYL CARBOXYLIC-ACIDS AND AMIDES [J].

ACHILEFU, S ;

MANSUY, L ;

SELVE, C ;

THIEBAUT, S .

JOURNAL OF FLUORINE CHEMISTRY, 1995, 70 (01) :19-26

[2]

Alsmeyer Y.W., 1994, Organofluorine Chemistry: Principles and Commercial Applications, P121, DOI [10.1007/978-1-4899-1202-2_5, DOI 10.1007/978-1-4899-1202-2_5]

[3]

[Anonymous], 1994, SURFACTANT SCI SERIE

[4]

Aresta M., 1987, NATO ASI SERIES C, V206

[5] LONG CHAIN ALKANOIC AND ALKENOIC ACIDS WITH PERFLUOROALKYL TERMINAL SEGMENTS [J].