Anionic metal dicyanamide networks with paramagnetic counter-cations

被引:85
作者
Batten, SR
Jensen, P
Moubaraki, B
Murray, KS
机构
[1] School of Chemistry, PO Box 23, Monash University
关键词
D O I
10.1039/b007080g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The M(bipy)(3)(2+) cations in the isomorphous structures of [M(bipy)(3)][M'(dca)(3)](2), [dca = dicyanamide, N(CN)(2)(-); M = Fe, M' = Mn 1, Fe 2 or M = Ni, M' = Mn 3] are contained within hexagonal windows of anionic 2D (6,3) M(dca)(3)(-) sheets; weak antiferromagnetic coupling is observed between metal centres within the anionic networks of all three compounds.
引用
收藏
页码:2331 / 2332
页数:2
相关论文
共 29 条
[1]   Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2- [J].
Batten, SR ;
Jensen, P ;
Moubaraki, B ;
Murray, KS ;
Robson, R .
CHEMICAL COMMUNICATIONS, 1998, (03) :439-440
[2]   Syntheses, structures and magnetism of α-Mn(dca)2, [Mn(dca)2(H2O)2]•H2O, [Mn(dca)2(C2H5OH)2]•(CH3)2CO, [Fe(dca)2(CH3OH)2] and [Mn(dca)2(L)2], where L = pyridine, CH3OH or DMF and dca- = dicyanamide, N(CN)2- [J].
Batten, SR ;
Jensen, P ;
Kepert, CJ ;
Kurmoo, M ;
Moubaraki, B ;
Murray, KS ;
Price, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17) :2987-2997
[3]  
BATTEN SR, 2000, J CHEM SOC DA
[4]  
Capes L, 2000, CHEM-EUR J, V6, P2246, DOI 10.1002/1521-3765(20000616)6:12<2246::AID-CHEM2246>3.0.CO
[5]  
2-X
[6]  
Coronado E, 2000, CHEM-EUR J, V6, P552, DOI 10.1002/(SICI)1521-3765(20000204)6:3<552::AID-CHEM552>3.0.CO
[7]  
2-U
[8]   1-D mixed stack of coordinated and uncoordinated radicals in MnII(NITpPy)4[N(CN)2]2 (NITpPy = nitronyl nitroxide radical) [J].
Dasna, I ;
Golhen, S ;
Ouahab, L ;
Peña, O ;
Guillevic, J ;
Fettouhi, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02) :129-132
[9]   Co-ordination complexes as organic-inorganic layer magnets [J].
Day, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (05) :701-705
[10]   Polymeric two- and three-dimensional transition-metal complexes comprising supramolecular host-guest systems [J].
Decurtins, S ;
Schmalle, H ;
Pellaux, R .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (02) :117-121