Anionic metal dicyanamide networks with paramagnetic counter-cations

被引：85

作者：

Batten, SR

Jensen, P

Moubaraki, B

Murray, KS

机构：

[1] School of Chemistry, PO Box 23, Monash University

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 23期

关键词：

D O I：

10.1039/b007080g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The M(bipy)(3)(2+) cations in the isomorphous structures of [M(bipy)(3)][M'(dca)(3)](2), [dca = dicyanamide, N(CN)(2)(-); M = Fe, M' = Mn 1, Fe 2 or M = Ni, M' = Mn 3] are contained within hexagonal windows of anionic 2D (6,3) M(dca)(3)(-) sheets; weak antiferromagnetic coupling is observed between metal centres within the anionic networks of all three compounds.

引用

页码：2331 / 2332

页数：2

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