Macropolyhedral boron-containing cluster chemistry.: Mixed and multiple cluster fusion in platinaborane chemistry and the structure of [(PMe2Ph)2PtB16H17PtB10H11(PMe2Ph)] as determined by synchrotron X-ray diffraction analysis

被引：14

作者：

Bould, J ^{[1
]}

Clegg, W

Kennedy, JD

Teat, SJ

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] CLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

[3] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 17期

关键词：

D O I：

10.1039/a803817a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Multiple cluster fusion between [(PMe2Ph)(2)PtB8H12] and molten B10H14, gave the 26-boron species [(PMe2Ph)(2)PtB16-H17PtB10H11(PMe2Ph)] which exhibits quite different structural and assembly features to the 26-boron species [(PMe3)(2)IrB26H24Ir(CO)(PMe3)(2)] previously prepared from [(PMe3)(2)(CO)HIrB8H12] and B10H14.

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页码：2777 / 2778

页数：2

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