A new and efficient electrosynthesis of polysubstituted cyclopropylphosphonates, using electrochemically activated magnesium

被引：20

作者：

Jubault, P

Goumain, S

Feasson, C

Collignon, N

机构：

[1] INSA, IRCOF, Lab Heterochim Organ, F-76131 Mt St Aignan, France

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

TETRAHEDRON | 1998年 / 54卷 / 49期

关键词：

D O I：

10.1016/S0040-4020(98)00925-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The diastereoselective electrosynthesis of polysubstituted a-chloro cyclopropylphosphonates is efficiently achieved by electroreduction of diisopropropyl trichloromethylphosphonate in the presence of Michael accepters, in a one-compartment cell equipped with a magnesium sacrificial anode. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：14767 / 14778

页数：12

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