Efficient preparation of terminal conjugated dienes by coupling of dienol phosphates with Grignard reagents under iron catalysis

被引：75

作者：

Cahiez, Gerard ^{[1
]}

Habiak, Vanessa ^{[1
]}

Gager, Olivier ^{[1
]}

机构：

[1] ESCOM, UPS, CNRS,UMR 8123, Lab Synth Organ Select & Chim Organomet SOSCO, F-95031 Neuville Sur Oise, Cergy Pontoise, France

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 12期

关键词：

D O I：

10.1021/ol800816f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient new route to prepare stereoselectively terminal conjugated dienes by coupling Grignard reagents and dienol phosphates in the presence of Fe(aCaC)(3) is described. The synthetic utility of this new iron-catalyzed procedure is illustrated by the synthesis of the pheromone of Diparopsis castanea according to a very expeditious strategy.

引用

页码：2389 / 2392

页数：4

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