The thermal decomposition of hydrocarbons .1. n-alkanes (C>=5).

被引：40

作者：

Safarik, I

Strausz, OP

机构：

[1] Department of Chemistry, University of Alberta, Edmonton

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1996年 / 22卷 / 03期

关键词：

D O I：

10.1163/156856796X00458

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pyrolysis of the long (C greater than or equal to 5) chain n-alkanes is reviewed with emphasis on the radical chain mechanism and on the reactions of the intermediate alkyl radicals. The effects of the experimental conditions and conversion on the types and distributions of the final products are also evaluated. The Arrhenius rate parameters are summarized for both the elementary steps and the overall decomposition reactions.

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页码：275 / 314

页数：40

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