IR characterizations of lithium imide and amide

被引:141
作者
Kojima, Y [1 ]
Kawai, Y [1 ]
机构
[1] Toyota Cent Res & Dev Labs Inc, Aichi 4801192, Japan
关键词
hydrogen storage materials; Gas-solid reaction; X-ray diffraction; Light absorption and reflection;
D O I
10.1016/j.jallcom.2004.10.063
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Li2NH was synthesized by decomposing of LiNH2 at 673 K under vacuum. Li2NH absorbed and desorbed 6.0-7.0 wt.% of hydrogen at 573-673 K in the pressure range of 9-0.001 MPa. According to the van't Hoff equation, the standard enthalpy change of the hydride reaction was about -66kJ/mol H-2. The hydrogen absorption and desorption by Li2NH was characterized by infrared spectroscopy. We found that IR bands at 3260 cm(-1) and 3315 cm(-1) of LiNH2 shift to 3180 cm(-1) and 3250 cm(-1) in the infrared spectrum of Li2NH. The broad IR bands shapes of the hydrogenated specimen (LiNH2) were related with the smaller crystallite size and/or the increasing crystallite disorder. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:236 / 239
页数:4
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